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SUMMARY:Ruthenium-Peptide Conjugates: from 'Peptide Origami' to Artificial
  Photosynthesis
DTSTART:20141001T144500
DTEND:20141001T160000
DTSTAMP:20260916T043423Z
UID:4513a65469bfe4c2885afdb3800beb8035764c5dccc164bace2a5dd3
CATEGORIES:Conferences - Seminars
DESCRIPTION:Dr. Hitoshi ISHIDA\, Department of Chemistry\, School of Scien
 ce\, Kitasato University\, Kanagawa \,Japan\nRuthenium-bipyridyl complexes
  have attracted much attention for their photo-functional properties: phot
 o-luminescence\, photo-sensitization\, or photo-catalytic ability. We have
  designed the peptides in which 5’-amino-2\,2’-bipyridyl-5-carboxylic 
 acid (5Bpy) as an unnatural amino acid is incorporated\, and have further 
 synthesized the ruthenium-peptide complexes. The ruthenium complex with th
 e peptide containing three residues of 5Bpy has been synthesized for the f
 irst time\, and has been named as “Peptide Origami”. We have also desi
 gned and synthesized the ruthenium-peptide complexes for the photo-catalyt
 ic CO2 reduction. In this lecture\, the mechanisms of the photochemical CO
 2 reduction by the ruthenium complexes and the design of the novel rutheni
 um-peptide complexes for the efficient catalysts will be described.
LOCATION:CH G1 495 https://plan.epfl.ch/?room==CH%20G1%20495
STATUS:CONFIRMED
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