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SUMMARY:Magneto - Excitons in New Emerging Materials
DTSTART:20150506T100000
DTSTAMP:20260511T125346Z
UID:f6bb52b6ecc6ae1b0d481246c5bee279b0ab53eaadbe34e6c7bc8658
CATEGORIES:Conferences - Seminars
DESCRIPTION:Prof. Paulina Plochocka\, Centre National de la Recherche Scie
 ntifique\nBio: Paulina Plochocka is currently chargé de recherche de 1èr
 e classe in Laboratoire National des Champs Magnétiques Intenses Toulouse
 \, CNRS. She received her MSc degree in Physics from Department of Physics
 \, Warsaw University\, Poland\, in  June 2000\, Ph.D. cum laude from Depa
 rtment of Physics\, Warsaw University\, Poland in November 2004 and Habili
 tation diriger des recherches from Université Joseph Fourier\, Grenoble\,
  France in 2011. From 2004 to 2006 she was holding Postdoctoral fellowship
  in Weizmann Institute of Science\, Israel\, in the group headed by Profes
 sor Israel Bar Joseph and from 2006 till 2011 she was Postdoctoral fellow 
 in Grenoble High Magnetic Field Laboratory\, France holding  Marie-Curie 
 fellowship. She joined LNCMI- Toulouse in 2011. Se works on magneto optica
 l properties of two dimensional semiconductors as well as single nano obje
 cts.\nThe talk will focus on the electronic properties of the excitons in 
 new emerging materials as atomically thin transition metals dichalcogenide
 s and solid-state perovskite investigated by magneto optics.\nReducing dim
 ensionality of the dichalcogens from 3D to 2D leads to new interesting opt
 ical properties e.g. opening a direct gap in the visible range. Moreover\,
  the physics of 2D semiconductors is known to be extremely rich once addit
 ional carriers are introduced into the system. In consequence\, optical sp
 ectra show the existence of not only neutral excitons but also of charged 
 ones. Hence\, the ability to control the exciton charge state in semicondu
 ctor structures\, which emit light at room temperature and in the visible 
 range\, is expected to open many possibilities for optoelectronics applica
 tions. I will discuss the possibilities of controlling the density of 2D c
 arriers in atomically thin layers of tungsten disulfide (WS2) and tungsten
  diselenide (WSe2) by simple below- or above-band gap. I will demonstrate 
 that the ratio between the concentrations of charged and neutral excitons 
 can be controlled by inter- or intraband illumination. This is direct proo
 f that we can control the density of 2D carriers in a single layer of WS2 
 using optical methods and opens a new venue for opto-electronic applicatio
 ns of this material. Additionally I will discuss the results of the optica
 l spectroscopy in high magnetic fields B < 65 T is used to reveal the very
  different nature of carriers in monolayer and bulk transition metal dicha
 lcogenides. In monolayer WSe2\, the exciton emission shifts linearly with 
 the magnetic field and exhibits a splitting which originates from the magn
 etic field induced valley splitting. The monolayer data can be described u
 sing a single particle picture with a Dirac-like Hamiltonian for massive D
 irac fermions\, with an additional term to phenomenologically include the 
 valley splitting. In contrast\, in bulk WSe2 where the inversion symmetry 
 is restored\, transmission measurements show a distinctly excitonic behavi
 or with absorption to the 1s and 2s states. Magnetic field induces a spin 
 splitting together with a small diamagnetic shift and cyclotron like behav
 ior at high fields\, which is best described within the hydrogen model.\nI
 n the end I will discuss the results of the measurement of the Exciton Bin
 ding Energy and effective masses for Charge carriers in Organic-Inorganic 
 Tri-halide Perovskites. Solid-state perovskite-based solar cells have made
  a dramatic impact on emerging PV research with efficiencies of over 17% a
 lready achieved but to date the basic electronic properties of the perovsk
 ites  such as the electron and hole effective masses and the exciton bind
 ing energy are not well known.  We have measured both for methyl ammonium
  lead tri-iodide using magneto absorption in very high magnetic fields up 
 to 150T showing that the exciton binding energy at low temperatures is onl
 y 16 meV\, a value three times smaller than previously thought and suffici
 ently small to completely transform the way in which the devices must oper
 ate. Landau level spectroscopy shows that the reduced effective mass of 0.
 104 me is also smaller than previously thought. We also observe Landau lev
 els in the high temperature as used for device production\, which has a ve
 ry similar effective mass and the analysis suggests an exciton binding ene
 rgy which is even smaller than in the low temperature phase.
LOCATION:BM 5202 https://plan.epfl.ch/?room==BM%205202
STATUS:CONFIRMED
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