Cold Molecular Ions in Traps: From Precision Measurements on Single Molecules to the Precise Control of Chemical Reactions

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Date 29.09.2016
Hour 16:3017:30
Speaker Prof. Stefan Willitsch
University of Basel
Department of Chemistry
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Category Conferences - Seminars
The recent progress in the preparation of neutral molecules and ions at temperatures close to the absolute zero point has paved the way for a range of new research directions at the interface between chemistry and physics. Ensembles of cold, spatially localized ions in traps, often referred to as Coulomb crystals, are particularly attractive systems in this context in which it is possible to observe, manipulate and control single isolated particles under precisely controlled conditions [1].     In the presentation, we will give an overview over some applications of cold molecular ions with recent examples from our work. We will discuss how single isolated molecules can be controlled on the quantum level which serves as a basis for molecular quantum technologies and precision measurements of molecular properties. We will then highlight experiments on chemical reactions between neutrals and ions at temperatures of a few millikelvin to illustrate exotic chemical processes that occur close to the absolute zero point of the temperature scale. Finally, we will present a new method to control chemical reactions of complex molecules by isolating distinct molecular conformations in an electric field and inducing their reaction with a localized reaction target of Coulomb-crystallized ions. The presentation will finish with an outlook on ongoing and future developments.     [1] S. Willitsch, Int. Rev. Phys. Chem. 31, 175 (2012)

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