Complex Hydrides as room-temperature solid electrolytes for rechargeable batteries

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Event details

Date 20.04.2016
Hour 16:0017:00
Speaker Dr. Didier Blanchard, Technical University of Denmark
Bio: D. Blanchard is, since 2013, Senior Researcher at the Technical University of Denmark, Department of Energy Conversion and Storage (Group leader Tejs Vegge). He joined the group in 2008, as postdoctoral researcher and then scientist. His research focuses on materials for energy storage: solid-­‐electrolytes, metal hydride batteries, ammonia storage and hydrogen storage in complex hydrides. He developed this later field of research while being postdoctoral researcher in Bjorn Hauback’s group at the institute for Energy Technology, Norway. D. Blanchard received his Ph.D. from the Université Joseph Fourier, Grenoble (France), after a university curriculum in applied physics, geophysics and atmospheric chemistry.
Location
EPFL Valais Zeuzier Conference Room
Category Conferences - Seminars
A central goal in current battery research is to increase the safety and energy density of Li-­‐ion batteries. Electrolytes  nowadays  typically  consist  of  lithium  salts  dissolved  in  organic  solvents.  Solid  electrolytes  could  facilitate  safer  batteries  with  higher  capacities,  as  they  are  compatible  with  Li-­‐metal  anodes, prevent Li dendrite formation, and eliminate risks associated with flammable organic solvents. Less than 10 years ago, LiBH4 was proposed as a solid-­‐state electrolyte. It showed a high ionic conductivity, but only at elevated temperatures. Since then a range of other complex metal hydrides has been reported to show similar characteristics.[1] Strategies have been developed to extend the high ionic conductivity of LiBH4 down to room temperature by partial anion substitution[2] or nanoconfinement.[3]
At DTU Energy, we have performed a thorough study on LiBH4, from the stability of its high temperature phase to characterization of all-­‐solid-­‐state lithium-­‐ion[4] and lithium-­‐sulfur batteries.[5] 
Using  a  wide  range  of  techniques,  such  as  Quasi-­‐elastic  Neutron  Scattering[6],  Positron  Annihilation,  Nuclear Magnetic Resonance and Electrochemical Measurements, we have studied the mechanisms of the lithium mobility and identified some fundamental principles giving opportunities for all-­‐solid-­‐state batteries  development  and  opening  new  research  direction  on  solid  electrolyte  based  on  complex  hydrides.

Practical information

  • General public
  • Free

Organizer

  • Prof. Andreas Zuettel

Contact

  • Annick Evequoz

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